Timeline of nickel

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This is a timeline of nickel. One of the most widely used metals on the planet, nickel is used in over 300,000 different products. It is most often found in steels and metal alloys. It is also used in the production of batteries and permanent magnets.[1]


Big picture

Time period Development summary
Ancient history Nickel is already used industrially as an alloying metal almost 2,000 years before it is isolated and recognized as a new element.[2] Its production sees an early development in China.
15th century German miners, who believe they can extract copper from nickel ores in Saxony, refer to the metal as kupfernickel ("the devil's copper"), partly due to their futile attempts to extract copper from the ore, but also likely in part due to the health effects caused by the high arsenic content in the ore.[1]
19th century Nickel's use in plating and alloys with copper and zinc begins.[3] Since the mid-century, nickel is the component of coins in the United States, India, Switzerland, and Canada.<?>
20th century Early in the century, the discovery of large scale deposits in Russia and South Africa makes large-scale production of nickel possible. A significant increase in demand of the metal results from World War I and World War II.[1] Along with development in society, the nickel industry develops rapidly since 1974, and the metal plays an important role in the stainless steel industry, battery industry and certain other industries. Nickel consumption increases greatly between 1974 and 2011.[4]
21st century More than 1.4 million tons of primary or new nickel is produced worldwide.[5] As of 2010, the largest producers of nickel are Russia, Canada, Australia, and Indonesia. The largest producers of refined nickel are Norilsk Nickel, Vale S.A., and Jinchuan Group Ltd. Only a small percentage of nickel is produced from recycled materials,[1] however, nickel recycling industry is developing fast.[4] Nickel is now recognized as one of the most valuable mined materials, making nickel mining an important industry.[5]

Full timeline

Year Event type Details Country/region
3500 BC Application Syrian bronzes contain a small amount of nickel.[4] Syria
1700 BC – 1400 BC Application Chinese manuscripts suggest use of white copper (cupronickel).[4] China
1500 BC Application Chinese documents from that time make reference to "white copper" (baitong), whis is very likely an alloy of nickel and silver.[1] China
235 BC Application Coins in China are made of nickel.[4][5][6][7] China
200 BC Application The Chinese make substantial amounts of a white alloy from zinc and copper-nickel ore found in Yunnan province. The alloy, known as pai-t'ung, is exported to the Middle East and even to Europe.[2] China
1751 Scientific development Swedish chemist Axel Fredrik Cronstedt first extracts pure nickel from the mineral niccolite (NiAs).[1][3][7]
1775 Scientific development Swedish mineralogist Torbern Bergman first fully purifies nickel.[8][9][10]
1776 Application It is established that the Chinese alloy pai-t'ung, now called nickel-silver, is composed of copper, nickel, and zinc.[2]
1796 Scientific development English chemist William Nicholson publishes First Principles of Chemistry. About nickel, Nicholson writes:
  This metallic substance has not been applied to any use; and the chief attention of those chemists who have examined it has been directed to obtain it in a state of purity; which however has not been accomplished... Nickel has been thought to be a modification of iron... So long as no one is able to produce this metal from pure iron or copper, and to explain in an intelligible way the process by which it can be generated, we must continue to regard it as a peculiar substance, possessing distinct properties. The general opinions of chemists concur in admitting the force of this reasoning.[11]
United Kingdom
1820 Application British chemist and natural philosopher Michael Faraday carries out several experiments in making nickel-containing steels, but fails to interest the steelmakers.[7] United Kingdom
1837 Application G. Bird describes electrodeposition of nickel chloride or sulphate on platinum. This process results in a thin crust of nickel on the platinum substrate.[12][13][14]
1840 Application Joseph Shore applies for a patent for nickel plating.[15]
1842 Application Böttger in Frankfurt succeeds in depositing nickel from a solution of nickel ammonium sulfate.[15] Germany
1844 Production Demand of nickel-silver is stimulated in England by the development of silver electroplating, for which it is found to be the most desirable base. The use of pure nickel as a corrosion-resistant electroplated coating would develop a little later.[2] United Kingdom
1860 Application An alloy of 25% nickel and 75% copper, essentially white in color, is adopted for coinage in Belgium.[2] Belgium
1865 Application An alloy copper-nickel is adopted for coinage in the United States.[2] United States
1865 Reserve Big deposits of nickel ores are discovered in New Caledonia.[7] New Caledonia
1868 Application W.H. Remington from Boston commences the deposition of nickel on a commercial scale using a nickel ammonium chloride solution.[15][16] United States
1869 Application Dr I. Adams in the United States patents a nickel ammonium sulphate bath.[17][12][15][16][18][19] United States
1877 Production Production of nickel starts in New Caledonia in the South Pacific.[2][20] New Caledonia
1878 Application Weston obtains a patent for the addition of boric acid to nickel plating solutions.[15]
1880 Application Nickel plating salts are being made in Vienna by Pfanhauser and in Birmingham by Canning.[16] Austria, United Kingdom
1881 Application Coins of nearly pure nickel are first used in Switzerland.[4][2] Switzerland
1889 Application British engineer James Riley makes a presentation to the Iron and Steel Institute of Great Britain on how the introduction of nickel could strenghten traditional steels. Riley's presentation results in a growing awareness of nickel's beneficial alloying properties and coincides with the discovery of large nickel deposits in New Caledonia and Canada.[1][21][22] United Kingdom
1890 Scientific development Nickel tetracarbonyl Ni(CO)4, is discovered. This compound, in which nickel exhibits a zero oxidation state, is used primarily as a carrier of carbon monoxide in the synthesis of acrylates (compounds used in the manufacture of plastics) from acetylene and alcohols. Nickel carbonyl is the first of a class of compounds called metal carbonyls to be discovered.[23]
1890 Scientific development A paper entitled Action of Carbon Monoxide on Nickel, by Ludwig Mond, Carl Langer and Friedrich Qpincke, describes the formation of a gaseous compound of nickel and carbon monoxide by the reaction of the latter with finely divided nickel.[22] United Kingdom
1898 Application Invar, an alloy containing 36% nickel, is discovered. With the balance iron, invar is notable for its extremely small thermal expansion. Along with later-developed nickel alloys, invar would have many applications ranging from thermostats to balance wheels for watches, metal-to-glass seals essential to electric lights, and radio tubes.[2][24][25]
1899 Technology W. Browne, of the Canadian Copper Co., develops an electrolytic process for the separation of nickel and copper.[22] Canada
1899 Technology German-born British chemist Ludwig Mond develops the now called Mond Process, for extraction and purification of nickel.[5] United Kingdom
1901 Technology Thomas Edison is awarded a patent por nickel-zinc (NiZn) chemistry. However, Edison would never be able to commercialize NiZn products. NiZn electrochemistry is found to have great potential because of its high energy density, high efficiency rating and temperature tolerance advantages compared to other battery chemistries.[26] United States
1905 Reserve The Copper Cliff-Sudbury, Ontario region in Canada becomes the world's largest source of nickel.[2] Canada
1915 Scientific development An investigation by H.T. Kalmus and coworkers dealing with cobalt as well as nickel is summarized in the publication Transactions of the Electrochemical Society. This work leads the authors to the opinion that nickel could not be plated under commercial conditions at current densities as high as those possible for cobalt.[18]
1916 Application O.P. Watts develops a rapid nickel plating bath.[15]
1918 Production The refining of nickel to the finished metal product begins in Canada with the building of Inco's refinery at Port Colborne, Ontario, using hydroelectric power from Niagara Falls.[27] Canada
1921 Technology The use of pH measurements for controlling nickel baths is first suggested. By the end of the decade, it would become a common industrial practice.[16]
1924 Application Nickel is used to plate automobile bumpers.[18]
1930 – 1935 Application Nickel-containing permanent-magnet alloys are developed in Japan.[2] Japan
1942 Technology W.A. Wesley and E.J. Roehl describe a bath of nickel sulfate, ammonium chloride and boric acid that could be operated at high pH to produce deposits with hardness in the range of 350-500 Vickers and tensile strength around 150,000 psi.[18]
1945 – 1955 Application Research by the International Nickel Company, Inc. (Inco) demonstrates the efficacy of multilayer coatings in enhancing corrosion protection of plated nickel.[18]
1959 Technology George Gutzeit, one of the inventors of the Kanigen process, presents a comprehensive discussion of the chemistry of the catalytic nickel process.[18][28]
1970 – 1975 Application The nickel-hydrogen battery is proposed as the leading candidate for rechargeable aerospace batteries.[29]
c.1979 Production Nickel production in Soviet Russia surpasses that in Canada.[2] Russia
1980 Application Falconbridge Nickel Co. and Inco introduce round forms of pure electrolytic nickel for plating.[18]
1993 Technology Stanford University chemist Morris Eisenberg creates a new electrolyte that enables a significant increase in the NiZn battery cycle life.[26] United States
1998 (December) Financial Nickel trades at a record low of 3730.50.[30]
2007 (May) Financial Nickel trades at an all time high of 54050.[30]
2010 Production As of date, the largest producers of nickel are Russia, Canada, Australia, and Indonesia.[1]

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References

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  2. 2.00 2.01 2.02 2.03 2.04 2.05 2.06 2.07 2.08 2.09 2.10 2.11 "Nickel processing". britannica.com. Retrieved 9 August 2018. 
  3. 3.0 3.1 "THE HISTORY OF NICKEL". twin-metals.com. Retrieved 9 August 2018. 
  4. 4.0 4.1 4.2 4.3 4.4 4.5 "Nickel: discovery and industry development". metalpedia.asianmetal.com. Retrieved 9 August 2018. 
  5. 5.0 5.1 5.2 5.3 "NICKEL MINING AND PROCESSING: EVERYTHING YOU NEED TO KNOW". generalkinematics.com. Retrieved 25 August 2018. 
  6. "Ni - Nickel". eperiodictable.com. Retrieved 25 August 2018. 
  7. 7.0 7.1 7.2 7.3 "Metal Story: Nickel (Ni)". oristarcorp.com. Retrieved 25 August 2018. 
  8. Holleman, A. F.; Wiberg, Egon; Wiberg, Nils. Inorganic Chemistry. 
  9. "What in the Word?! The bedeviling origins of 'nickel'". blog.oxforddictionaries.com. Retrieved 25 August 2018. 
  10. Morris, Richard. The Last Sorcerers: The Path from Alchemy to the Periodic Table. 
  11. Enghag, Per. Encyclopedia of the Elements: Technical Data - History - Processing - Applications. 
  12. 12.0 12.1 "The History of Nickel Plating". thomasnet.com. Retrieved 9 August 2018. 
  13. Dennis, J. K.; Such, T. E. Nickel and Chromium Plating. 
  14. Wang, J; Gabe, D.R. "The chemistry of nickel electroplating solutions". 
  15. 15.0 15.1 15.2 15.3 15.4 15.5 "Nickel Plating Primer". pfonline.com. Retrieved 25 August 2018. 
  16. 16.0 16.1 16.2 16.3 Dennis, J. K.; Such, T. E. Nickel and Chromium Plating. 
  17. Popular Science Aug 1884. 
  18. 18.0 18.1 18.2 18.3 18.4 18.5 18.6 "A Retrospective View of Nickel Plating". pfonline.com. Retrieved 25 August 2018. 
  19. "Week 31". acs.org. Retrieved 25 August 2018. 
  20. "Nickel - Mining and metallurgy". croixdusud.info. Retrieved 25 August 2018. 
  21. Sparrow, Giles. Nickel. 
  22. 22.0 22.1 22.2 Dennis, W.H. Metallurgy: 1863-1963. 
  23. "Nickel". britannica.com. Retrieved 9 August 2018. 
  24. Instruments & Control Systems, Volume 13. Chilton Company, 1940. 
  25. "Invar". britannica.com. Retrieved 25 August 2018. 
  26. 26.0 26.1 "History". zincfive.com. Retrieved 9 August 2018. 
  27. "Nickel". uwaterloo.ca. Retrieved 25 August 2018. 
  28. "Historical Highlights of Electroless Plating". pfonline.com. Retrieved 25 August 2018. 
  29. "A History of Nickel Hydrogen Batteries" (PDF). electrochem.org. Retrieved 9 August 2018. 
  30. 30.0 30.1 "Nickel". tradingeconomics.com. Retrieved 9 August 2018.